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SCF-Calculations as Tool to Interprete Reaction Pathes - The Cases of C02 Loss from Ionized ClCH2-COOCH3 and C2H4 Loss from Ionized (CH3)2N-COCH2X

Gernot Frenking ; Institut fur Organische Chemie, Technische Universitat Berlin, Strasse des 17. Juni 135, D-1000 Berlin 12, W.-Germany
Helmut Schwarz ; Institut fur Organische Chemie, Technische Universitat Berlin, Strasse des 17. Juni 135, D-1000 Berlin 12, W.-Germany


Puni tekst: engleski pdf 2.555 Kb

str. 185-190

preuzimanja: 220

citiraj


Sažetak

The localization of transition states as saddle points having
one negative eigenvalue of the force-constant matrix provides
important informations on the energy hyperface of chemical reactions.
It can be used for determining the reaction path of unusual
experimental results and is demonstrated for the title reactions.

Ključne riječi

Hrčak ID:

194223

URI

https://hrcak.srce.hr/194223

Datum izdavanja:

30.6.1983.

Posjeta: 636 *