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An Investigation of the Electrochemical Reactions of a Nickel Cyanide Complex at Mercury Electrode by Cyclic Voltammetry

D. Čukman ; Laboratory of Electrochemistry and Surface Phenomena, »Ruder Boskovic« Institute, 41001 Zagreb, Croatia, Yugoslavia
V. Pravdić ; Laboratory of Electrochemistry and Surface Phenomena, »Ruder Boskovic« Institute, 41001 Zagreb, Croatia, Yugoslavia

Sažetak

Cyclic voltammograms obtained for the reduction and reoxidation
reactions of nickel cyanide complex with and without an
excess of free cyanide in solution are shown and discussed. These
reactions could best be described as an ECE mechanism, accompanied
by a fast equilibrium disproportionation reaction between
the two Ni(I) complex intermediates.

Ključne riječi

Hrčak ID:

195948

URI

https://hrcak.srce.hr/195948

Datum izdavanja:

22.12.1978.

Posjeta: 552 *