Skoči na glavni sadržaj

Croatica Chemica Acta, Vol. 48 No. 4, 1976.

Izlaganje sa skupa

Bond Formation in Electrosorbates

J. W. Schultze ; Institut fur Physikalische Chemie und Quantenchemie der Freien Universitat Berlin

Puni tekst: engleski pdf 2.550 Kb

str. 643-649

preuzimanja: 152

citiraj

Sažetak

The electrosorption valency y is defined and its meaning is
thoroughly discussed. Exiptl. dent. of y is demonstrated for systems
Au/Bi3+ and Pt/Cu2+. It is found that for homonuclear ions in aq.
solns. the ratio y/z, where z stands for Nernst valency, is successfully
correlated with the electro.negativity difference I XM - Xs I of
the electrode metal M and the sorbate S. For small electronegativity
differences, y/z •is close to unity indicating large covalency.
Bond formation in electrosorbates in non-aq. solvents and at single
crystal plames of various orientations are briefly discussed.

Ključne riječi

Hrčak ID:

196451

URI

https://hrcak.srce.hr/196451

Datum izdavanja:

22.12.1976.

Posjeta: 540 *