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Heterocycles. CI. Syntheses and Isomerizations of Some Allylthio Nitrogen Heterocycles

M. Kočevar ; Department of Chemistry, University of L j ubljana, 61000 Ljubljana, Slovenia, Yugoslavia
B. Stanovnik ; Department of Chemistry, University of L j ubljana, 61000 Ljubljana, Slovenia, Yugoslavia
M. Tišler ; Department of Chemistry, University of L j ubljana, 61000 Ljubljana, Slovenia, Yugoslavia


Puni tekst: engleski pdf 6.462 Kb

str. 457-464

preuzimanja: 158

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Sažetak

Allylthio nitrogen heterocycles were isomerized under the
influence of base into the corresponding propenylthio analogs. Subsequently,
isomerization of the resultant cis-propenylthio compounds
afforded the trans-isomers. In the case of 2-allylthiobenzothiazole
isomerization is followed by hydrolytic cleavage of the side chain.
Similar behaviour was observed in the 1,2,3-benzotriazine series.

Ključne riječi

Hrčak ID:

197016

URI

https://hrcak.srce.hr/197016

Posjeta: 244 *