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Mass Spectra of Labeled Cyclopentanols

K. Humski ; Institute »Ruder Boskovic«, 41000 Zagreb
L. Klasinc ; Institute »Ruder Boskovic«, 41000 Zagreb
D. Kovačević ; Institute »Ruder Boskovic«, 41000 Zagreb

Sažetak

The fragmentation of cyclopentanol has been studied by employing
the deuterium labeling technique. Starting from the molecular
ion the following specific processes could be established:
loss of H from the position 1, loss of CH3 formed mainly from 2
(or 5) position after a-scission, loss of H 2 0 as a 1,3-elimination,
and loss of C2H 5 generated from 2 and 3 or 4 and 5 positions plus
one hydrogen from position 5 or 2, respectively. The results are
discussed.

Ključne riječi

Hrčak ID:

197032

URI

https://hrcak.srce.hr/197032

Datum izdavanja:

30.6.1973.

Posjeta: 1.337 *