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CND0/2 Calculation of Dipole Moments of trans-1,2-Dipyridylethylenes

J. V. Knop ; Institute of Physical Chemistry, University of Dusseldorf, Germany


Puni tekst: engleski pdf 2.396 Kb

str. 419-421

preuzimanja: 251

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Sažetak

Recently, the dipole moments of the six isomeric trans-1,2-dipyridylethylenes (DPE) have been reported1• With the exception of 1,2-di-(pyridyl-4)-ethylene (4,4-DPE) all isomers can exist in several configurations depending on the relative
position of the two nitrogen atoms. Thus, for the six trans-isomers, 15
non-identical configurations are possible2 (Fig. 1). In the determination and discussion of the observed dipole moment, the knowledge of the amount of each configuration present in the measured sample is of great importance. Two procedures have so far been used to obtain this information.

Ključne riječi

Hrčak ID:

197037

URI

https://hrcak.srce.hr/197037

Datum izdavanja:

30.6.1973.

Posjeta: 685 *