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Metal Hydrolysis and Oxide-Hydroxide Precipitation

S. Y. Tyree ; College of William and Mary, Williamsburg, Virgini a, 23185, U.S.A .

Puni tekst: engleski pdf 4.281 Kb

str. 195-198

preuzimanja: 118



Methods used to study the hydrolysis behavior of metal cations
and metallate anions are reviewed. Some results in the cases of
bismuth(III), iron(III), aluminum(III), gallium(III), and zirconium(IV)
show that the approach to equilibrium can vary from immeasurably
fast to immeasurably slow. Thus, caution is urged in the use of
published equilibrium constants relating hydrolyzed solute species
and oxide/hydroxide heterogeneous phases.

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