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On the Reaction of 2-Phthalimido-1-octadecanal and 2-Methoxy-1-octadecanal with Nitromethane

J. Pluščec ; Department of Chemistry, Faculty of Medicine, University of Zagreb and Department of Biochemistry, Institute »Rud er Boskovic«, Zagreb, Croatia, Yugoslavia
A Kisić ; Department of Chemistry, Faculty of Medicine, University of Zagreb and Department of Biochemistry, Institute »Rud er Boskovic«, Zagreb, Croatia, Yugoslavia
M . Proštenik ; Department of Chemistry, Faculty of Medicine, University of Zagreb and Department of Biochemistry, Institute »Rud er Boskovic«, Zagreb, Croatia, Yugoslavia

Sažetak

The preparation of 2-phthalimido-1-octadecanal (III) and
2-methoxy-1-octa decanal (XII) is described. Condensa tion of III
with nitromethane in the presencl of potassium carbonate yields
a mixture of 1-nitro-2-hydroxy.l -phthalimido-nonadecane (IV),
1 - nitro - 2 - hydroxy-3 - (o-carbox , enzamido)-nonadecane (V) and
1-nitr~-3-p?thalimido-1-i;ionadec e.n ~ (VI) . Similar condensation of
XII with mtromethane yields 1-mtifo-2-hydroxy-3-methoxynonadecane
(XIII) . Catalytic reduction of 1VI and XIII furnishes the corresponding
saturated amino compounds (VII and XIV).

Ključne riječi

Hrčak ID:

208345

URI

https://hrcak.srce.hr/208345

Datum izdavanja:

31.7.1963.

Posjeta: 651 *