Croatica Chemica Acta, Vol. 34 No. 4, 1962.
Izvorni znanstveni članak
Hybridization in Planar XY 4 Molecules
M. Randić
; Institute »Ruder Boskovic« Zagreb, Croatia, Yugoslavia
Sažetak
Maximum overlap hybriid orbitals for planar XY4 molecules
are described assuming various orbitals for ligand and central
atoms. Distribution of s and d character in square snp2d2-n hybridization
as a tunction of ilnteratomilc distances, and for different
relamive effective charges iof bonded atoms .is g.iven. Maximum
overlap hybdds, when compared with those based on Pauling's
criterion of hybrid 1strength, show a generally smaller contribuition
of d z2 orbdtal in the hybnidizati'on, especially evident
for ~\ligand< μm etal, when in SOlffie cases they _ reduce to simple
dsp2 hybrids . Calculait:i.ons are based
data for Slaiter functions .
Ključne riječi
Hrčak ID:
208385
URI
Datum izdavanja:
15.1.1963.
Posjeta: 886 *