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Studies in the Sphingolipids Series. XVIII. Synthesis and Resolution of 1-Hydroxy-2-aminoeicosane (C20-Sphingine)

M. Munk-Weinert ; Department of Chemistry, Medical Faculty, University of Zagreb, Zagreb, Croatia, Yugoslavia
M. Proštenik ; Department of Chemistry, Medical Faculty, University of Zagreb, Zagreb, Croatia, Yugoslavia


Puni tekst: engleski pdf 6.620 Kb

str. 197-202

preuzimanja: 74

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Sažetak

The preparation of racemic 1-hydroxy-2-aminoeicosane (C20 -
-sphingine) is described. The racemic base was resolved into the
optical antipodes via the diastereomeric L-glutamates. N-Acetyland
O,N-diacetyl derivatives of the enantiomeric bases are described.
D-Configuration is assigned to the (-) base.

Ključne riječi

Hrčak ID:

208593

URI

https://hrcak.srce.hr/208593

Posjeta: 212 *