Original scientific paper
Optical characteristics of bismuth sulfide (Bi2S3) thin films
S. Mahmoud
; Physics Department, National Research Centre, Cairo, Egypt
A. H. Eid
; Physics Department, National Research Centre, Cairo, Egypt
H. Omar
; Physics Department, National Research Centre, Cairo, Egypt
Abstract
Thin films of bismuth sulfide (Bi2S3) were grown by two deposition techniques, by thermal evaporation and by chemical deposition. The thermally deposited reactions consisted in depositing the individual elements, namely bismuth and sulfur, sequentially from a tungsten boat source and allowing the layers to interdiffuse to form the compound during the heat-treatment. The chemical deposition was based on the reaction between the triethanolamine compex of Bi3+ ions and thiourea in basic media. Scanning electron microscope and X-ray diffraction analysis were made on as-deposited and on annealed films to determine their structure. The different electronic transitions and the optical constants are determined from the transmision and reflection data of these thin films for normal incidence. The optical gaps of Bi2S3 films show a remarkable dependence on the preparation method.
Keywords
Hrčak ID:
299848
URI
Publication date:
1.7.1997.
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