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Kinetics of Oxidation of Heterocyclic Compounds by Quinolinium Dichromate

Hauzachin Saunte ; Department of Chemistry, National Institute of Science Education and Research, Bhubaneswar 751 005, India
Girija S. Chaubey ; Department of Chemistry, National Institute of Science Education and Research, Bhubaneswar 751 005, India
Mahendra K. Mahanti ; Department of Chemistry, National Institute of Science Education and Research, Bhubaneswar 751 005, India


Puni tekst: engleski pdf 310 Kb

str. 291-298

preuzimanja: 1.335

citiraj


Sažetak

Quinolinium dichromate in sulfuric acid oxidized heterocyclic aldehydes (to the corresponding
acids) and heterocyclic carboxylic acids (to the corresponding hydroxy-substituted acids) in acetic acidwater
medium (vol. ratio, v(water)/v(acetic acid) = 50:50). The kinetic results supported a mechanistic
pathway proceeding via a rate-determining decomposition of the chromate ester.

Ključne riječi

kinetics, oxidation, heterocyclic compounds, quinolinium dichromate

Hrčak ID:

62206

URI

https://hrcak.srce.hr/62206

Posjeta: 1.821 *