Original scientific paper

https://doi.org/10.5562/cca2475

12-(N-Methylnitrilium)monocarba-closo-dodecaborate Ylide

Filip Šembera ; Institute of Organic Chemistry and Biochemistry AS CR, v.v.i., Flemingovo nám. 2, 16610 Prague, Czech Republic
Alexander Higelin ; Institute of Organic Chemistry and Biochemistry AS CR, v.v.i., Flemingovo nám. 2, 16610 Prague, Czech Republic
Ivana Císařová ; Department of Inorganic Chemistry, Charles University, Hlavova 2030, 12843 Prague 2, Czech Republic
Josef Michl orcid.org/0000-0002-4707-8230 ; Institute of Organic Chemistry and Biochemistry AS CR, v.v.i., Flemingovo nám. 2, 16610 Prague, Czech Republic;Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, United States

Abstract

The syntheses, spectral characterization, and crystal structures of 12-(N-methylnitrilium)-monocarba-closo-dodecaborate and 12-(N-methylamidinium)-monocarba-closo-dodecaborate ylides
are reported. The carborate anion behaves as an inert and non-conjugating negative
charge.

Keywords

ylide; carborane; monocarba-closo-dodecaborate; nitrilium

Hrčak ID:

131529

URI

https://hrcak.srce.hr/131529

Publication date:

22.12.2014.

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