Original scientific paper

Kinetics of Base Hydrolysis of Low-spin Iron(II)-diimine Complexes in Methanol-Water Mixtures

Ezz-Eldin A. Abu Gharib ; Faculty of Science, South Valley University, Sohag 82524, Egypt
Nrinder Gosal ; Department of Chemistry, University of Leicester, Leicester LE1 7RH, U.K.
John Burgess ; Department of Chemistry, University of Leicester, Leicester LE1 7RH, U.K.

Abstract

Rate constants are reported for base hydrolysis of several low-spin iron(II)-diimine complexes, mostly of polydentate ligands, in water and in aqueous methanol (up to 40% methanol). Rate constant trends from these and earlier studies of a variety of iron(II)-diimine complexes are compared and discussed in terms of ligand structure, ligand substituents, and solvation properties of the various complexes.

Keywords

low-spin iron(II)-diimine complexes; base hydrolysis; kinetics

Hrčak ID:

131860

URI

https://hrcak.srce.hr/131860

Publication date:

1.8.2001.

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