Croatica Chemica Acta, Vol. 64 No. 2, 1991.
Original scientific paper
Experimental Conditions for the Electrochemical Activation of an Electrodeposited Ruthenium Electrode
Marijan Vuković
; Laboratory of Electrochemistry and Surface Phenomena, Ruder Bošković Institute, Zagreb, Croatia, Yugoslavia
Abstract
Several types of electrodeposited ruthenium electrodes on a platinum substrate have been studied. The first type was prepared by a galvanostatic deposition using 40 mA cm-2 current density and varying deposition time from 1 to 60 min. A porous layer was obtained which exhibited passive behaviour during potentiodynamic polarization at positive potentials before commencement of the oxygen evolution reaction. This layer has been electrochemically activated to a second type of electrode by square wave pulses between -0.2 and + 0.85 V vs. SCE. The complete reduction of the oxide is a necessary condition for the activation process. A potentiostatic electrodeposition and a galvanostatic electrodeposition using low current density and short deposition time produced electrodes whose voltammetric behaviour was similar to a bulk ruthenium electrode in acid solution.
Keywords
Hrčak ID:
137351
URI
Publication date:
15.10.1991.
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