Croatica Chemica Acta, Vol. 61 No. 1, 1988.
Original scientific paper
Kinetic and Equilibrium Thermodynamic Description of the Interaction of Desferrioxamine B and Acethydroxamic Acid with Iron(III) in Acid Aqueous Perchlorate
Mladen Biruš
; Faculty of Pharmacy and Biochemistry, University of Zagreb, Zagreb, Croatia, Yugoslavia
Gordana Krznarić
; Faculty of Pharmacy and Biochemistry, University of Zagreb, Zagreb, Croatia, Yugoslavia
Nikola Kujundžić
; Faculty of Pharmacy and Biochemistry, University of Zagreb, Zagreb, Croatia, Yugoslavia
Marijan Pribanić
; Faculty of Pharmacy and Biochemistry, University of Zagreb, Zagreb, Croatia, Yugoslavia
Abstract
Same activation parameters of the stepwise formation and
hydrolysis of the iron(III) complexes with desferrioxamine B and
acethydroxamic acid, as well as the enthalpy and entropy of the
overall reactions are reported. The mechanism of the formation and hydrolysis of the iron-(III)-hydroxamate complexes is disscused in view of the obtained data.
Keywords
Hrčak ID:
175868
URI
Publication date:
28.4.1988.
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