Croatica Chemica Acta, Vol. 61 No. 4, 1988.
Original scientific paper
Electronic Spectra of Cyano-5-phenyltetrazoles
I. Janić
; Institute of Physics, Faculty of Science, University of Novi Sad, Novi Sad, Yugoslavia
M. Kakaš
; Institute of Physics, Faculty of Science, University of Novi Sad, Novi Sad, Yugoslavia
P. Baluk
; Luminescence Research Group, Institute of Experimental Physics, University of Gdansk, Gdansk, Poland
A. Kubicki
; Luminescence Research Group, Institute of Experimental Physics, University of Gdansk, Gdansk, Poland
A. Kawski
; Luminescence Research Group, Institute of Experimental Physics, University of Gdansk, Gdansk, Poland
Abstract
Absorption and luminescence spectra of ortho-, meta- and para-
cyano-5-phenyltetrazole in aqueous solutions at room and low
temperature were measured. Investigations wene carried out in
super acidic (H; = -8) to basic (pR = 12)media. Three dissociation
forms were identified (anion, molecule and cation), and the corresponding acid-base equilibrium constants in the ground state,
speetrophotometrically, and in the first excited singlet state from
the titration curves and by Forster cycle were determined.
Keywords
Hrčak ID:
176004
URI
Publication date:
30.12.1988.
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