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Original scientific paper

Oxozirconium(IV) Complexes of Di-n-Butyl and Di-n-Pentyl Sulphoxides

R. K. Agarwal ; Department of Chemistry, Lajpat Rai (Post-Graduate) College, Sahibabad-201 005 (Ghaziabad), India


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Abstract

The synthesis and physical properties of ZrO++ complexes of di-n-butylsulphoxide (DBuSO) and di-n-pentylsulphoxide. (DPnSO) with the general composition ZrOX2·2L (X = Cl, Br, I, NCS, NCSe OI' N03 and L = DBuSO or DPnSO) and ZrO(CI04)2' 4L are reported together with molecular conductivity, molecular weights and IR. In all the complexes, the sulphoxides are coordinated to zirconium(IV) through their lone oxygen atom. Thermal behaviour of the complexes has also been studied.

Keywords

Hrčak ID:

176402

URI

https://hrcak.srce.hr/176402

Publication date:

23.12.1987.

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