Croatica Chemica Acta, Vol. 59 No. 3, 1986.
Original scientific paper
A Formal Pro of of Vessel-Shape Dependency of the Ideal-Gas One-Particle Partition Function of Translation
Zdenek Slanina
; Department of Chemistry, Faculty of Science, Hokkaida University, Sapporo 060, Japan
Abstract
An erroneous limiting behaviour of the conventional translational partition function q has been pointed out. Some general features of the exact translational partition function Q are given. A formal proof that Q (from a rigorous point of view) depends on the shape of vessel is presented. A possible relation of the result to experimental observations is briefly discussed.
Keywords
Hrčak ID:
177304
URI
Publication date:
25.7.1986.
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