Croatica Chemica Acta, Vol. 57 No. 4, 1984.
Original scientific paper
Polarized Infrared Spectra of Tolane Single Crystal
Lidija Colombo
; Rudjer Boskovic Institute, P. P. 1016, 41001 Zagreb, Croatia, Yugoslavia
Goran Baranović
; Rudjer Boskovic Institute, P. P. 1016, 41001 Zagreb, Croatia, Yugoslavia
James R. Durig
; Department of Chemistry, University of South Carolina, Columbia, SC 29208, USA
Ann E. Stanley
; Department of Chemistry, University of South Carolina, Columbia, SC 29208, USA
Abstract
Polarized infrared spectra of an oriented and very thin tolane
crystal have been measured in the 3500--50 cm-1 region. The symmetry
of the infra red active internal vibrations is proposed on the
basis of the oriented gas model. The application of the vibrational
spectroscopy in studying the conformation of the free tolane molecule
is discussed.
Keywords
Hrčak ID:
194131
URI
Publication date:
20.10.1984.
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