Croatica Chemica Acta, Vol. 57 No. 4, 1984.
Review article
Structural Characteristics of ACuCl3 Salts
Roger D. Willett
; Chemistry Department, Washington State University, Pullman, WA 99164-4630, USA
Urs Geiser
; Chemistry Department, Washington State University, Pullman, WA 99164-4630, USA
Abstract
The coordination geometries and the electronic structures
found in trichlorocuprates(II) are reviewed. Trichlorocuprates occur
in two types: dimers and chains. The crystal chemistry of both
types is discussed. A simple electrostatic argument, charge compensation,
allows the prediction of the overall structure. Interest·
in the former class is focused on the different ways of dimer
stacking, and on low-dimensional physics in the latter.
Keywords
Hrčak ID:
194143
URI
Publication date:
20.10.1984.
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