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Review article

Structural Characteristics of ACuCl3 Salts

Roger D. Willett ; Chemistry Department, Washington State University, Pullman, WA 99164-4630, USA
Urs Geiser ; Chemistry Department, Washington State University, Pullman, WA 99164-4630, USA


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Abstract

The coordination geometries and the electronic structures
found in trichlorocuprates(II) are reviewed. Trichlorocuprates occur
in two types: dimers and chains. The crystal chemistry of both
types is discussed. A simple electrostatic argument, charge compensation,
allows the prediction of the overall structure. Interest·
in the former class is focused on the different ways of dimer
stacking, and on low-dimensional physics in the latter.

Keywords

Hrčak ID:

194143

URI

https://hrcak.srce.hr/194143

Publication date:

20.10.1984.

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