Review article

Structural Characteristics of ACuCl3 Salts

Roger D. Willett ; Chemistry Department, Washington State University, Pullman, WA 99164-4630, USA
Urs Geiser ; Chemistry Department, Washington State University, Pullman, WA 99164-4630, USA

Abstract

The coordination geometries and the electronic structures
found in trichlorocuprates(II) are reviewed. Trichlorocuprates occur
in two types: dimers and chains. The crystal chemistry of both
types is discussed. A simple electrostatic argument, charge compensation,
allows the prediction of the overall structure. Interest·
in the former class is focused on the different ways of dimer
stacking, and on low-dimensional physics in the latter.

Keywords

Hrčak ID:

194143

URI

https://hrcak.srce.hr/194143

Publication date:

20.10.1984.

Visits: 627 *