Original scientific paper

An Investigation of the Electrochemical Reactions of a Nickel Cyanide Complex at Mercury Electrode by Cyclic Voltammetry

D. Čukman ; Laboratory of Electrochemistry and Surface Phenomena, »Ruder Boskovic« Institute, 41001 Zagreb, Croatia, Yugoslavia
V. Pravdić ; Laboratory of Electrochemistry and Surface Phenomena, »Ruder Boskovic« Institute, 41001 Zagreb, Croatia, Yugoslavia

Abstract

Cyclic voltammograms obtained for the reduction and reoxidation
reactions of nickel cyanide complex with and without an
excess of free cyanide in solution are shown and discussed. These
reactions could best be described as an ECE mechanism, accompanied
by a fast equilibrium disproportionation reaction between
the two Ni(I) complex intermediates.

Keywords

Hrčak ID:

195948

URI

https://hrcak.srce.hr/195948

Publication date:

22.12.1978.

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