Preliminary communication

Crystal and Molecular Structure of (S)- a -(p Chlorobenzenesulphonamido)- B-Propiothiolactone

I. Milinović ; Department of Organic Chemistry and Biochemistry, FacuUy of Science, University of Zagreb
A. Bezjak ; Department of Chemistry, Faculty of Pharmacy and Biochemistry, University of Zagreb
D. Fleš ; Research and Development Institute, IN A, 41000 Zagreb, Yugoslavia

Abstract

These substances give by polymerization the optically active polythiolesters. The polymers may be of chemical and biological interest because they represent a new class of nonamide-bonded polycysteins. The proposed mechanism of polymerization4 suggests the opening of the B-propiothiolactone ring by S2-C8 bond rupture. It has been found that the rate of polymerization of substrates with different substituents on the benzene ring depends on the nature of the p~substituents.

Keywords

Hrčak ID:

197000

URI

https://hrcak.srce.hr/197000

Publication date:

15.4.1974.

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