Original scientific paper

Synthesis of Di(s-triazinyl) Sulphides and Disulphides. The-Promoting Effect of Oxidants on the Cleavage of the Thioether Bond

P. Mildner ; Laboratory of Biochemistry, Faculty of Technology, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia
Branka Mihanović ; Laboratory of Biochemistry, Faculty of Technology, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia
M . Poje ; Laboratory of Biochemistry, Faculty of Technology, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia

Abstract

Synthesis of a number of di(s-triazinyl) sulphides and disu1phides
is described. The behaviour of these compounds on
oxidative attack has been examined. It has been found that instead
of the expected sulphoxide and/or sulphone formation upon
oxidation, a simple scission of the thioether linkage takes place,
yielding a hydroxytriazine and the corresponding disulphide.

Keywords

Hrčak ID:

197019

URI

https://hrcak.srce.hr/197019

Publication date:

12.11.1973.

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