Croatica Chemica Acta, Vol. 45 No. 1, 1973.
Conference paper
Metal Hydrolysis and Oxide-Hydroxide Precipitation
S. Y. Tyree
; College of William and Mary, Williamsburg, Virgini a, 23185, U.S.A .
Abstract
Methods used to study the hydrolysis behavior of metal cations
and metallate anions are reviewed. Some results in the cases of
bismuth(III), iron(III), aluminum(III), gallium(III), and zirconium(IV)
show that the approach to equilibrium can vary from immeasurably
fast to immeasurably slow. Thus, caution is urged in the use of
published equilibrium constants relating hydrolyzed solute species
and oxide/hydroxide heterogeneous phases.
Keywords
Hrčak ID:
197060
URI
Publication date:
15.6.1973.
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