Croatica Chemica Acta, Vol. 28 No. 1, 1956.
Original scientific paper
The Kinetics of Oxidation of Aldehydes to Acidsand Acid Anhydrides. II
I. Brihta
; Institute of Industrial Research, Zagreb, Croatia, Yugoslavia
T. Vrbaški
; Institute of Industrial Research, Zagreb, Croatia, Yugoslavia
Abstract
Continuing our studies on the catalytic decomposition of peracids into acids and on the interaction of peracids with aldehydes into acids and acid anhydrides, we examined the influence of other mixed catalysts, i. e. manganese and copper butyrates and iron and copper butyrates on reaction rates. They were found to be in good accordance with thermodynamic data. The anhydride formation in the presence of a mixture of manganese and copper catalyst was investigated and found to be slightly inferior to the yield obtained with a pure manganese catalyst.
Keywords
Hrčak ID:
247077
URI
Publication date:
2.4.1956.
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