Original scientific paper

Vibrational spectra and structural studies of Hg-As-S glasses

Natalja Mateleshko ; Uzhgorod State University, Department of Solid State Electronics, 32 Voloshin Street, Uzhgorod 294000, Ukraine
Vladymyr Mitsa ; Uzhgorod State University, Department of Solid State Electronics, 32 Voloshin Street, Uzhgorod 294000, Ukraine
Alexandr Kikineshi ; Uzhgorod State University, Department of Solid State Electronics, 32 Voloshin Street, Uzhgorod 294000, Ukraine

Abstract

Structural interpretation of Raman and IR spectra, and X-ray diffraction study give evidence to the fact that the adding of mercury into binary glass-forming system causes the formation of α-HgS and β-As4S4 at CHg > 2 at.%. Slow quenching of the melt of HgAsS2 compound results in the separation of α-HgS and β-As4S4. In the chain-like model of a-As2S3 structure, the addition of Hg atoms results in the increase of chain dimensions from 1.42 to 1.8 nm.

Keywords

Hg-As-S glasses; Raman and IR spectra; X-ray diffraction; separation of a-HgS and b-As4S4; chain-like model of a-As2S3 structure

Hrčak ID:

300921

URI

https://hrcak.srce.hr/300921

Publication date:

1.3.1999.

Article data in other languages: croatian

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