Croatica Chemica Acta, Vol. 96 No. 2, 2023.
Preliminary communication
https://doi.org/10.5562/cca4013
Comparison of Radon Adsorption on Hematite and Charcoal Activated Powder in Air
Vanja Radolić
orcid.org/0000-0002-7843-2626
; Josip Juraj Strossmayer University of Osijek, Department of Physics, Trg Ljudevita Gaja 6, HR-31000 Osijek, Croatia
Goran Šmit
orcid.org/0009-0004-5965-8488
; Josip Juraj Strossmayer University of Osijek, Department of Physics, Trg Ljudevita Gaja 6, HR-31000 Osijek, Croatia
*
Igor Miklavčić
; Josip Juraj Strossmayer University of Osijek, Department of Physics, Trg Ljudevita Gaja 6, HR-31000 Osijek, Croatia
Marina Poje Sovilj
orcid.org/0000-0003-0381-8556
; Josip Juraj Strossmayer University of Osijek, Department of Physics, Trg Ljudevita Gaja 6, HR-31000 Osijek, Croatia
* Corresponding author.
Abstract
Adsorption of radon in the air was investigated on hematite, α-Fe2O3, and charcoal activated powder. Hematite had almost doubled efficiency in comparison to charcoal activated powder in the same experimental conditions but over a significantly longer period. Adsorption isotherms revealed a typical Langmuir shape on hematite and almost linear on activated charcoal. Linear models of Langmuir, Freundlich and Dubinin-Radushkevich isotherms showed that radon adsorption on both adsorbents is a favourable chemical process, with stronger interactions on hematite, that takes place forming a monolayer of adsorbed radon. The kinetic analysis confirmed forming of a monolayer on both adsorbents and two rate-controlling steps during radon adsorption on hematite, instead of one on activated charcoal, which could be considered as a reason of slower rate of process on hematite.
Keywords
hematite; activated charcoal; radon; adsorption; air
Hrčak ID:
309415
URI
Publication date:
17.10.2023.
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