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Original scientific paper

https://doi.org/10.54820/entrenova-2023-0007

Towards Optimal Production of Graphene by Electrolysis in Molten Salts Using Machine Learning

Viktor Andonovikj ; Faculty of Electrical Engineering and Information Technologies, North Macedonia
Mimoza Kovaci Azemi orcid id orcid.org/0000-0002-2933-5408 ; Faculty of Geodetic Sciences and Technology, “Xasan Pristina” University, Mitrovica, Republic of Kosovo
Beti Andonovic orcid id orcid.org/0000-0002-5386-457X ; Faculty of Technology and Metallurgy, St. Cyril and Methodius University, Skopje, North Macedonia
Aleksandar Dimitrov ; Faculty of Technology and Metallurgy, St. Cyril and Methodius University, Skopje, North Macedonia


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Abstract

Graphene is very exciting and one of the best materials in the last decade. The interest in producing non-expensive and high-quality graphene is of great interest to many Departments of materials and researchers worldwide. The main goal of this research considers the design, development, and optimisation of new technology for producing graphene by electrolysis in molten salts using constant cell voltage, reversing cell voltage, and constant overpotential and reversing overpotential methods. Compared to other processes, the electrolysis process is simple, ecological, and economical. Furthermore, it offers possibilities to control various parameters: type of electrolyte, applied voltage, current density, temperature and type of graphite used as a row material for synthesis of graphene. The underlying relationship between the parameters and the quality of the graphene is obtained through an explainable tree-based Machine Learning (ML) model. We trained the model by using the production process parameters as input attributes and the quality of the produced graphene as a target variable. Domain experts provide labels regarding the quality of each experimental instance in our data set. We propose using the extracted rules from the model to serve as a blueprint for optimal graphene production by electrolysis in molten salts. Choosing the correct values for the process parameters results in high-yield graphene production, up to ten times cheaper than the one produced with other existing technologies.

Keywords

graphene; electrolysis; graphite; molten salts; machine learning

Hrčak ID:

319466

URI

https://hrcak.srce.hr/319466

Publication date:

21.7.2024.

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