Original scientific paper

https://doi.org/10.5562/cca1972

Highly Exfoliated Graphite Fluoride as a Precursor for Graphene Fluoride Dispersions and Films

Vladimir Efimovich Fedorov orcid.org/0000-0002-1057-3342 ; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia
Ekaterina Dmitrievna Grayfer orcid.org/0000-0002-2994-959X ; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia
Viktor Gerasimovich Makotchenko ; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia
Albert Semenovich Nazarov ; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia
Hyeon-Jin Shin ; Samsung Advanced Institute of Technology, Yongin, Gyeonggi, 446-712 Korea
Jae-Young Choi ; Samsung Advanced Institute of Technology, Yongin, Gyeonggi, 446-712 Korea

Abstract

We synthesized highly exfoliated graphite fluoride of approximate composition C2F by treating highly exfoliated graphite with ClF3. The formed material was found to be dispersible in solvents giving 1 to 5 layered fluorinated graphene. Dispersions successfully formed in polar organic solvents capable of establishing hydrogen bonds. The highest stability is achieved in branched alcohols such as tert-butanol. The dispersions may be further processed into thin films by vacuum filtration technique. Also, composite multilayered films of graphene fluoride and graphene may be prepared. (doi: 10.5562/cca1972)

Keywords

graphite; fluoride; graphene; dispersion; film

Hrčak ID:

80446

URI

https://hrcak.srce.hr/80446

Publication date:

30.4.2012.

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