Review article

https://doi.org/10.5562/cca1864

Thermodynamics of the Reactions at Solid/Liquid Interfaces

Nikola Kallay ; Laboratory of Physical Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia
Tajana Preočanin orcid.org/0000-0002-6670-6503 ; Laboratory of Physical Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia
Davor Kovačević ; Laboratory of Physical Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia
Johannes Lützenkirchen ; Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie (KIT), Postfach 3640, 76021 Karlsruhe, Germany
Mario Villalobos ; Environmental Bio-Geochemistry Group, Facultad de Química and Instituto de Geología, Universidad Nacional Autónoma de México (UNAM), México 04510, D.F.

Abstract

The present review discusses the state of the art of the thermodynamic treatment for variable
charge at solid/liquid interfaces. The most important equations are given for the case of generic surface
sites. This can easily be extended to the more general case for multiple surface sites. Detailed aspects involving
thermodynamic standard states of simple and multidentate surface complexes are addressed, and
relationships between the commonly-used empirical adsorption isotherms and the Surface Complexation
Model are presented. (doi: 10.5562/cca1864)

Keywords

surface charge; solid/liquid interface; surface complexation model

Hrčak ID:

69686

URI

https://hrcak.srce.hr/69686

Publication date:

30.5.2011.

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