Croatica Chemica Acta, Vol. 86 No. 2, 2013.
Original scientific paper
https://doi.org/10.5562/cca2097
Manganese/TiO2 Composites Prepared and Used for Photocatalytic Active Textiles
Boris Mahltig
; University of Applied Sciences Niederrhein, Faculty of Textile and Clothing Technology, Webschulstrasse 31, 41065 Mönchengladbach, Germany
Helfried Haufe
; Gesellschaft zur Förderung von Medizin-, Bio- und Umwelttechnologien e.V., GMBU e.V., Department: Functional Coatings, Postfach 520165, D-01317 Dresden, Germany
Chang Woo Kim
; Sogang University, Department of Chemistry, 1 Shinsu-dong, Mapo-gu, Seoul 121-742, Korea
Young Soo Kang
; Sogang University, Department of Chemistry, 1 Shinsu-dong, Mapo-gu, Seoul 121-742, Korea
Emanuel Gutmann
; Gesellschaft zur Förderung von Medizin-, Bio- und Umwelttechnologien e.V., GMBU e.V., Department: Photonics & Sensorics, Felsbachstrasse 7, D-07745 Jena, Germany
Tilmann Leisegang
; Saxray GmbH, Helmholtzzentrum Dresden-Rossendorf, Bautzner Landstraße 400, D-01328 Dresden, Germany
Dirk Carl Meyer
; Technische Universität Bergakademie Freiberg, Institut für Experimentelle Physik, D-09596 Freiberg, Germany
Abstract
Manganese/TiO2 composites are prepared by a solvothermal process starting from the precursors
titanium propoxide and manganese nitrate. The solvothermal processes are driven at temperatures of 140
°C or 180 °C. The formation of anatase as crystalline TiO2-phase was determined by XRD for preparation
conditions at 180 °C. The occurance of crystalline phases in nanometer scale is determined further by
TEM. The prepared manganese/TiO2-composites are further investigated as coating onto viscose textile.
The photocatalytic activity of those composites was determined by degradation of organic dye stuff under
illumination with UV-light. The effect of photocatalytic dye degradation is also investigated in presence
of H2O2. The prepared textile coatings exhibit a high capability for dye decomposition under the chosen
arrangement of investigations. For this reason, the prepared coated textile materials could be of high interest
for industrial applications, for example, as filter material for cleaning waste water from dyeing processes.
(doi: 10.5562/cca2097)
Keywords
titania; photocatalysis; H2O2; hydrogenperoxide; Acid Orange
Hrčak ID:
105388
URI
Publication date:
1.7.2013.
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