Original scientific paper

https://doi.org/10.15255/CABEQ.2013.1860

Investigation of Leaching Kinetics of Ulexite Waste in Oxalic Acid Solutions

S. U. Bayca ; University of Kirikkale, Faculty of Engineering, Department of Metallurgy and Materials Engineering, 71450 Yahsihan, Kirikkale, Turkey
F. Kocan ; Celal Bayar University, Science and Arts Faculty, Chemistry Department, 45030 Muradiye, Manisa, Turkey
Y. Abali ; Celal Bayar University, Science and Arts Faculty, Chemistry Department, 45030 Muradiye, Manisa, Turkey

Abstract

The dissolution of ulexite waste in oxalic acid solutions was studied in a batch reactor after characterization of the waste by X-ray diffraction (XRD) analysis and X-ray fluorescence (XRF) analysis. The dissolution parameters in this study were acid concentration, stirring rate, and reaction temperature. The experimental data were examined using homogeneous and heterogeneous kinetic models, and the dissolution kinetics of the waste was determined to be a first-order reaction control model. The activation energy of ulexite waste in oxalic acid solution was also calculated. It was observed that the dissolution rate increased with increasing reaction temperature, stirring rate and acid concentration. The kinetic model of the dissolution process was determined to be a first-order reaction control model. The activation energy was found to be 41.09 kJ mol–1.

Keywords

ulexite waste; leaching kinetics model; dissolution; boric acid; oxalic acid

Hrčak ID:

128029

URI

https://hrcak.srce.hr/128029

Publication date:

10.10.2014.

Visits: 1.770 *