Original scientific paper
https://doi.org/10.5599/jese.2014.0049
Voltammetric determination of hydroxylamine in water and waste water samples using a NiO nanoparticle/new catechol derivative modified carbon paste electrode
Mahbobeh Moazampour
; Department of Chemistry, Graduate University of Advanced Technology, Kerman, Iran
Fahimeh Tahernejad-Javazmi
; Department of Chemistry, Graduate University of Advanced Technology, Kerman, Iran
Maryam Salimi-Amiri
; Department of Physics, Sari Branch, Islamic Azad University, Sari, Iran
Hassan Karimi-Maleh
; Department of Physics, Sari Branch, Islamic Azad University, Sari, Iran
Mehdi Hatami
; Polymer Research Laboratory, University of Bonab, Bonab, Islamic Republic, Iran
Abstract
A (9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboximido)-4-ethylbenzene-1,2-diol (DED) modified NiO/NPs carbon paste electrode “(DED/NiO nanoparticle (NiO/NPs)/CPE) was constructed for determination of hydroxylamine (HX). The cyclic voltammogram showed that the electrocatalytic oxidation of HX at the surface of DED/NiO/NPs/CPE occurs at a potential of about 800 mV less positive than with an unmodified electrode. Square-wave voltammetry results presented that the electrocatalytic oxidation peak currents of HX in pH 8.0 had two linear dynamic ranges in the range of 0.1 to 2.0 and 2.0 to 400.0 µM HX, with a detection limit of 0.07 µM. The kinetic parameters such as electron transfer coefficient a (0.47) and rate constant (2.454 × 103 M-1 s-1) were determined for the chemical reaction between HX and DED. Finally, this method was evaluated for the determination of HX in water and waste water samples.
Keywords
Hydroxylamine; NiO nanoparticle; water and waste water analysis; sensor; voltammetry
Hrčak ID:
130194
URI
Publication date:
6.12.2014.
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