Croatica Chemica Acta, Vol. 87 No. 3, 2014.
Original scientific paper
https://doi.org/10.5562/cca2506
Theory of Anodic Stripping Square Wave Voltammetry on Spherical Mercury Electrodes
Šebojka Komorsky-Lovrić
; Department of marine and environmental research, “Ruđer Bošković” Institute, 10000 Zagreb, Croatia
Milivoj Lovrić
orcid.org/0000-0002-6421-1398
; Department of marine and environmental research, “Ruđer Bošković” Institute, 10000 Zagreb, Croatia
Abstract
Relationships between dimensionless anodic stripping square-wave voltammetric net peak currents and the dimensionless inverse electrode radius are curves with two asymptotes that depend on the duration of accumulation. The theory applies to reversible reduction of amalgam forming ions on stationary mac-ro and micro spherical and hemispherical mercury electrodes.
Keywords
square wave voltammetry; spherical electrodes; theory; microelectrode
Hrčak ID:
130524
URI
Publication date:
18.11.2014.
Visits: 2.082 *