Preliminary communication

Direct Synthesis of Dinuclear Carboxylate-Bridged Ruthenium(I) Complexes from the Substitution of the Formate Bridge in Compound

Josep Soler ; Departament de Quimica, Universitat Autònoma de Barcelona, 08193-Bellaterra, Barcelona, Spain
Josep Ros ; Departament de Quimica, Universitat Autònoma de Barcelona, 08193-Bellaterra, Barcelona, Spain

Abstract

An easy method of preparation of Ru2(//2-02CR)2(CO)4(PPh3)2 compounds from the formate derivative Ru2(t(2-02CH)2(CO)4(PPh3)2 is reported. Four carboxylate containing alkene groups complexes were prepared using this method. The new complexes were identified by elemental analyses, IR, 1H-NMR, 31P-NMR and 13C-NMR spectroscopies.

Keywords

Hrčak ID:

136702

URI

https://hrcak.srce.hr/136702

Publication date:

1.11.1995.

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