Croatica Chemica Acta, Vol. 67 No. 2, 1994.
Conference paper
The Structure of Zeolite and Aluminophosphate Molecular Sieves
Venčeslav Kaučič
; National Institute of Chemistry and University of Ljubljana P. O. Box 30, 61115 Ljubljana, Slovenia
Abstract
Zeolites and other molecular sieves are microporous crystalline solids whose main uses are in catalysis, ion-exchange reactions and as adsorbents. Their crystalline structures and different ways of identification of molecular sieve structure are reviewed, together with a short introduction into the catalytic activity of these materials. Synthesis and structural overview of aluminophosphates, a new and fast-growing family of microporous materials, are presented and strategy for introducing different metal atoms into aluminophosphate framework is discussed. These chemical framework modifications lead to a broad range of structure types and offer a nearly unlimited number of design parameters for the tailoring of catalityc and adsorptive properties of aluminophosphate materials. Our results in the areas of synthesis and X-ray diffraction structural characterization of metal-substituted aluminophosphates are reviewed.
Keywords
Hrčak ID:
136889
URI
Publication date:
1.8.1994.
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