Original scientific paper

Reactive Intermediates and the Question of Concertedness in the Catalytic Power of Enzymes

Richard L. Schowen ; Departments of Chemistry and Biochemistry, University of Kansas, Lawrence, Kansas 66045-0046, USA
K. Barbara Schowen ; Departments of Chemistry and Biochemistry, University of Kansas, Lawrence, Kansas 66045-0046, USA

Abstract

Conditions derived from physical organic chemistry, which govern the circumstances under which the evolution of enzyme catalysis can lead to the conversion of an on-enzyme stepwise reaction into an on-enzyme concerted reaction, are presented and discussed.

Keywords

Hrčak ID:

137135

URI

https://hrcak.srce.hr/137135

Publication date:

15.10.1992.

Visits: 827 *