Short communication, Note

Description of Molecular Distortions: IV. Relationships Between the Distortion and the Hydrogen Bond Strength for Some Compounds Containing HSO₄ Ions

V. Petruševski ; Institute of Chemistry, Faculty of Science, Skopje, Yugoslavia
A. W. Al-Kassdb ; Department of Chemistry, La Trobe University, Bundoora, Victoria, 3038, Australia
B. D. James ; Department of Chemistry, La Trobe University, Bundoora, Victoria, 3038, Australia
J. Liesegang ; Department of Chemistry, La Trobe University, Bundoora, Victoria, 3038, Australia

Abstract

Several methods are known for describing the distortions of tetrahedral molecules. In the present paper, some correlations between the hydrogen bond strength and the different measures for the distortions of HS04~ ions are evaluated. In terms of the distortion indices the rasults reflect similar trends to those calculated for phosphates1. It is found that weaker hydrogen bonding as accompanied by larger distortions of the HS04 tetrahedra.

Keywords

Hrčak ID:

137399

URI

https://hrcak.srce.hr/137399

Publication date:

10.8.1990.

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