Original scientific paper

New Syntheses of Thiazole and Thiophene Derivatives

Mahfouz A. Abdelaziz ; Chemistry Department, Faculty of Science, Cairo University, Cairo, Egypt
S. A. El-Sharabasy ; Chemistry Department, Faculty of Science (Girls) Al-Azhar University, Cairo, Egypt
S. A. Mansour ; Chemistry Department, Faculty of Education at Kafr El-Sheikh, Tanta, University, Tanta, Egypt
S. M. Abdel Gawad ; Chemistry Department, Faculty of Science (Girls) Al-Azhar University, Cairo, Egypt

Abstract

A novel synthesis of methylenebis(A2-l,3-thiaizoline-4-one) via reaction of chloroacetic acid wiith (A2-l,3-thiazoline-4-one- -2-yl)thioacetamide and a new route for synthesis of 2-aryl-4- -oxothiolane-3,3-dicarbonitrile via the reaction of thioglycolic acid with 3-aryl-2-cyanothioacrylamides are reported. The reaction of aromatic aldehydes and arenediazonium Chloride with active methylene compounds is discussed. The structures of all new compounds are established and the mechanism proposed for some reactions.

Keywords

Hrčak ID:

137403

URI

https://hrcak.srce.hr/137403

Publication date:

10.8.1990.

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