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Original scientific paper

Chiroptical Properties and Absolute Configuration of Chiral, Open Chain Di- and Tri-substituted Allenes: a Polarizability Approach

Carlo Rosini ; Centro di Studio del C.N.R. per le Macromolecole Stereordinate ed Otticamente Attive, Dipartimento di Chimica e Chimica Industriale, via Risorgimento 35, 56100 Pisa - Italia
Maurizio Zandomeneghi ; Centro di Studio del C.N.R. per le Macromolecole Stereordinate ed Otticamente Attive, Dipartimento di Chimica e Chimica Industriale, via Risorgimento 35, 56100 Pisa - Italia
Piero Salvadori ; Centro di Studio del C.N.R. per le Macromolecole Stereordinate ed Otticamente Attive, Dipartimento di Chimica e Chimica Industriale, via Risorgimento 35, 56100 Pisa - Italia


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Abstract

A second order treatment of the optical activity of chiral diand
tri-substituted open chain allenes, by means of the polarizability
model of DeVoe, makes it possible to establish a simple relationship between optical rotatory power and absolute configuration of these compounds.

Keywords

Hrčak ID:

175503

URI

https://hrcak.srce.hr/175503

Publication date:

10.8.1989.

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