Croatica Chemica Acta, Vol. 62 No. 3, 1989.
Original scientific paper
Preparation of Chiral Oxoazetidinesulfinates
Jure J. Herak
; Research Institute PLIVA, Zagreb, Croatia, Yugoslavia
Miće Kovačević
; Research Institute PLIVA, Zagreb, Croatia, Yugoslavia
Branimir Gašpert
; Research Institute PLIVA, Zagreb, Croatia, Yugoslavia
Abstract
Diastereomeric oxoazetidinesulfinates IV were prepared from
penicillanate S,S-dioxide (Sulbactam) via sulfinic acid I and sulfinyl
chlorides II. Both epimers IVa and IVb gave the same oxoazetidinesulfonate V upon oxidation.
The lH NMR spectra of IVa and IVb correspond to those of
alfa- and beta-S-oxide of penicillanates.
Keywords
Hrčak ID:
175812
URI
Publication date:
10.10.1989.
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