Croatica Chemica Acta, Vol. 60 No. 3, 1987.
Conference paper
Enthalpies of Dilution of Bile Salt Solutions: Sodium Taurodeoxycholate and Sodium Taurocholate
Nikola Kallay
; Laboratory of Physical Chemistry, Faculty of Science, University of Zagreb, P. O. Box 163, 41001 Zagreb, Yugoslavia
Miroslav Čolić
; Laboratory of Physical Chemistry, Faculty of Science, University of Zagreb, P. O. Box 163, 41001 Zagreb, Yugoslavia
Vladimir Simeon
; Institute for Medical Research and Occupational Health, P. O. Box 291, 41001 Zagreb, Yugoslavia
Josip P. Kratohvil
; Department of Chemistry and Institute of Colloid and Surface Science, Clarkson University, Potsdam, New York 13676, U.S.A.
Abstract
The enthalpies of dilution of solutions of two bile salts in water and aqueous NaCI were measured over a range of solute concentrations encornpassing the critical micellization concentrations (c.m.c.). The compounds were sodium taurodeoxycholate and sodium taurochoiate. An isoperibolic reaction calorimeter was used. The observed changes of enthalpies of dilution as a function of surfactant and NaCI concentrations were related to the c.m.c.values, micellar aggregation numbers and counterion binding.
Keywords
Hrčak ID:
176379
URI
Publication date:
25.8.1987.
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