Croatica Chemica Acta, Vol. 60 No. 4, 1987.
Original scientific paper
Synthesis and Characterization of Amorphous Nickel(II) Aluminosilicate
Nevenka Z. Rajić
; Faculty of Technology and Metallurgy, University of Beograd, P. O. Box 494, Yu-11001 Beograd, Yugoslavia
Đorđe R. Stojaković
; Faculty of Technology and Metallurgy, University of Beograd, P. O. Box 494, Yu-11001 Beograd, Yugoslavia
Abstract
Amorphous aluminosilicates containing about 12 wto °/0 nickel
have been synthesized bycation exchange. Approximately 40°/0 of the nickel content is present in the form of octahedral [Ni\H20)6]2+ ions while the bulk of NF+ is coordinated both by I-hO molecules and by oxygen atoms of the aluminosilicate framework. When the materials are heated in air at 350 -c, a change in the nickel coordination environment/geornetry and possibly also a partial oxidation take place.
Keywords
Hrčak ID:
176400
URI
Publication date:
23.12.1987.
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