Original scientific paper

Calculation of Phase Diagrams of Ternary Reciprocal Molten Salt Mixtures. The System Li+-K+-F--Cl-

Istvan J. Zsigrai ; Institute of Chemistry, Faculty of Science, University of Novi Sad, Novi Sad
Katalin Szecsenyi-Meszaros ; Institute of Chemistry, Faculty of Science, University of Novi Sad, Novi Sad
Ivanka Paligorić ; Institute of Chemistry, Faculty of Science, University of Beograd, Yugoslavia
Ivan J. Gal ; Institute of Chemistry, Faculty of Science, University of Beograd, Yugoslavia

Abstract

In order to calculate phase diagrams of ternary reciprocal molten salt systems, the conformal ionic solution theory and an earlier developed binary ionic-interaction model has been used to derive the excess chemical potentials of the components. A computer program has been developed which delivers data on phase equilibria in the form of tables of liquidus temperatures against the composition of the system. The method of calculation has been applied to the system Li+-K+-F--Cl- and the calculated phase diagram is compared with the experimental one.

Keywords

Hrčak ID:

177738

URI

https://hrcak.srce.hr/177738

Publication date:

22.5.1985.

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