Original scientific paper

Asymmetric Chemical Synthesis of (R)- and (S)-Citramalate in High Enantiomeric Purity

Stephen V. Frye ; W. R. Kenan, Jr. Laboratories, University of North Carolina, Chapel Hill, North Carolina 27514, U.S.A.
Ernest L. Eliel ; W. R. Kenan, Jr. Laboratories, University of North Carolina, Chapel Hill, North Carolina 27514, U.S.A.

Abstract

Both enantiomers of dimethyl 2-acety1citramalate have been
asymmetrically synthesized in over 96% enantiomeric excess and
good overall chemical yield (500/0)from 2-keto-1,3-oxathianes 1a,
and 1b.

Keywords

Hrčak ID:

178051

URI

https://hrcak.srce.hr/178051

Publication date:

6.3.1986.

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