Original scientific paper

https://doi.org/10.5562/cca3126

Visible Light Promoted Allylic C–H Oxidation

Vishal Srivastava ; Department of Chemistry, United College of Engineering & Management, Naini, Allahabad - 211010, India
Pravin K. Singh ; Food Analysis and Research Lab, Centre of Food Technology, University of Allahabad, Allahabad - 211002, India
Praveen P. Singh orcid.org/0000-0002-6087-4709 ; Department of Chemistry, United College of Engineering & Research, Naini, Allahabad - 211010, India

Abstract

A mild and efficient one-pot visible light-induced method has been developed for the allylic oxidation. The oxidation of allylic systems has played a prominent role in this context as possibly the most widely applied C–H functionalization, owing to the utility of enones. The allylic C–H oxidation is relatively simple and predictable, even on a preparative scale, because active species generated at the allylic position are stabilized by the double bond.

This work is licensed under a Creative Commons Attribution 4.0 International License.

Keywords

eosin Y; visible-light; organophotoredox; allylic oxidation; C–H oxidation; enones

Hrčak ID:

184812

URI

https://hrcak.srce.hr/184812

Publication date:

18.12.2017.

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