Original scientific paper
https://doi.org/10.5599/jese.409
Simulation of square wave voltammetry of three electrode reactions coupled by two reversible chemical reactions
Milivoj Lovrić
orcid.org/0000-0002-6421-1398
; Divkovićeva 13, Zagreb 10090, Croatia
Abstract
Three fast and reversible electrode reactions that are connected by two reversible chemical reactions that are permanently in the equilibrium are analysed theoretically for square wave voltammetry. The dependence of peak potentials on the dimensionless equilibrium constants of chemical reactions is calculated. The influence of the basic thermodynamic parameters on the square wave voltammetric responses is analysed.
Keywords
ECECE mechanism; equilibrium conditions; voltammetry; theory
Hrčak ID:
185731
URI
Publication date:
15.8.2017.
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