Preliminary communication

Allylic Cations in Solvolysis. A Case of Non-Participation

Mladen Ladika ; Department of Chemistry, Faculty of Natural Sciences and Mathematics, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia
Dionis E. Sunko ; Department of Chemistry, Faculty of Natural Sciences and Mathematics, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia

Abstract

The rate constants and secondary deuterium Isotope ef'fects
are measured in the solvo'lysis of various allyHc p-nitrobenzoates.
The obtained results are explained by differences in inductive
effects o>f vardous groups in the side-chain. These results
are in keeping with the stepwise mechanism according to which
neighboiring group n- and n-paxticiipation is not revealed in the
studied solvCJ!lytic reactions.

Keywords

Hrčak ID:

194181

URI

https://hrcak.srce.hr/194181

Publication date:

15.2.1984.

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