Original scientific paper

Conformational Analysis of Bis-(N,N-dimethylvalinato)copper(II): a Possible Explanation of the Enantioselectivity Effect

Nenad Raos ; Institute for Medical Research and Occupational Health, 41001 Zagreb, Croatia, Yugoslavia
Vladimir Simeon ; Institute for Medical Research and Occupational Health, 41001 Zagreb, Croatia, Yugoslavia

Abstract

The conformation:il space of the stereoisomers of bis-(N,N-.
-dimethylvalinato)copper(II) was investigated by the consistent
force field (CFF) method. The calculated enantioselectivities, defined
as Gibbs energy differences between M(L-ligand)2 and M(L-
ligand) (o-ligand) complexes, qualitatively agree with the experimentally
observed values.

Keywords

Hrčak ID:

194242

URI

https://hrcak.srce.hr/194242

Publication date:

15.4.1983.

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